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Allgemeine Chemie II — Energy, Equilibrium & Electrons (Uni Hamburg prep)

by Mona
The second half of Hamburg's first-semester Allgemeine Chemie, where most first-years lose points. Discover why reactions happen at all (thermodynamics), why some spontaneous reactions never seem to occur (kinetics), how far reactions actually go (equilibrium), and how these same ideas govern acids, buffers, batteries, and electrolysis. Builds directly on Allgemeine Chemie I, one focused idea at a time, ending with the tools to walk into the exam confident.
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Why Reactions Happen (Thermodynamics)

Lesson 1
The Pouch That Freezes Itself image

The Pouch That Freezes Itself

A hand warmer heats itself and a cold pack freezes itself — both entirely on their own, which should be impossible if reactions only happen because they release energy.
Start
Lesson 2
The Heat of a Reaction Nobody Can Run image

The Heat of a Reaction Nobody Can Run

No calorimeter has ever watched graphite turn into diamond — so how does every data book list the heat of that change to two decimal places?
Start
Lesson 3
Entropy — The Real Driver image

Entropy — The Real Driver

Ice melts, perfume spreads, gases mix — with nothing pushing them. Meet the quantity that quietly runs the universe.
Locked till you take the prior lesson
Lesson 4
Gibbs Free Energy image

Gibbs Free Energy

One equation folds heat and disorder into a single verdict: will it happen? And temperature casts the deciding vote.
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How Fast & How Far (Kinetics and Equilibrium)

Lesson 5
Why Spontaneous ≠ Fast image

Why Spontaneous ≠ Fast

Your diamond is thermodynamically doomed — it 'wants' to become pencil lead. So why will it outlast you by a billion years?
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Lesson 6
The Dynamic Standstill image

The Dynamic Standstill

A sealed flask of reacting gases stops changing colour. Has the reaction finished? The molecules would strongly disagree.
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Lesson 7
Le Chatelier & the Haber Process image

Le Chatelier & the Haber Process

An equilibrium that fed billions of people — and the industrial compromise that had to be struck to make it pay.
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Lesson 8
K meets ΔG image

K meets ΔG

Two modules, two separate quantities — thermodynamic drive and equilibrium position. They turn out to be the same statement.
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Acids, Bases & Buffers

Lesson 9
What Makes an Acid an Acid? image

What Makes an Acid an Acid?

Water is neither acid nor base — except that it is quietly both, and that double life sets the entire pH scale.
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Lesson 10
The pH Scale & Strong Acids image

The pH Scale & Strong Acids

Stomach acid and drain cleaner differ by a factor of a hundred trillion. One small scale tames that entire range.
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Lesson 11
Weak Acids & Ka image

Weak Acids & Ka

Vinegar and hydrochloric acid at the same concentration behave nothing alike. Concentration is clearly not the whole story.
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Lesson 12
Buffers — Blood's Secret Weapon image

Buffers — Blood's Secret Weapon

Your blood must stay within 0.05 pH units or you die. Meanwhile you produce acid all day long. How?
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Redox & Electrochemistry

Lesson 13
Redox Revisited & Oxidation Numbers image

Redox Revisited & Oxidation Numbers

No oxygen, no obvious electron handover — yet it is unmistakably a redox reaction. You will need better bookkeeping.
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Lesson 14
Galvanic Cells — Chemistry Makes Electricity image

Galvanic Cells — Chemistry Makes Electricity

Drop zinc into copper sulfate and you get warm liquid. Separate the two halves and you get electricity. Why does separation matter?
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Lesson 15
Nernst, Batteries & Electrolysis image

Nernst, Batteries & Electrolysis

Every dying battery is an equilibrium running out of road — and run current backwards and you can force chemistry uphill.
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